Thus stability of alkaline earth metal hydroxides decreases with decrease in lattice enthalpy as the size of alkali earth metal cations increases down the group. 2 M N O 3 h e a t 2 M n O 2 + O 2 Nitrates of group -1 and group-2 metals are all soluble in water. Stability of oxides decreases down the group. ... Solubility of the carbonates increases as you go down Group 1. On heating alkali metal (Na, K, Rb and Cs) decompose to form metal nitrites and oxygen. Alternative Thermal decomposition of group 2 carbonates practical. (ii) All the alkaline earth metals form oxides of formula MO. The same thing applies to the cation while progressing down the group. The hydroxides of the Group II metals, which may be used in thermochemical water-splitting cycles, have been investigated thermoanalytically. Hence, more is the stability of oxide formed, less will be stability of carbonates. The solubility of alkaline metal carbonates and sulphates decreases with decrease in hydration energy as we move down the group. The increasing thermal stability of Group 2 metal salts is consistently seen. Magnesium hydroxide: this is the most insoluble and can be brought as a suspension in water. Since beryllium oxide is high stable, it makes BeCO 3 unstable. Solution: Stability of ionic compounds decreases with decrease in lattice enthalpy. The thermal stability of the hydrogencarbonates. Hence, barium hydroxide is more soluble than beryllium hydroxide. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. The size of B e 2 + is smallest and the size of B a 2 + is highest. So what causes this trend? Place the other end of the delivery tube into a test tube which is one third full of limewater. A higher temperature is required to decompose Ba(NO 3) 2 as compared to Mg(NO 3) 2. The solubilities of these salts further increase on descending the group. There is no reaction or precipitate when dilute sodium hydroxide is added to a solution of Sr 2+ or Ba 2+ ions. The respective TG- and DSC-curves are represented. The hydroxides. As the size increases, the decrease in the lattice energy is much more than the decrease in the hydration energy. BeCO 3 â BeO + CO 2. Attach the delivery tube to the test tube. This is why the solubility of Group 2 hydroxides increases while progressing down the group. Now let's look at $\ce{SO4^2-}$. Sulphates: Thermal stability The sulphates of group-1 and group-2 metals are all thermally stable. The least soluble hydroxide in Group 1 is lithium hydroxide - but it is still possible to make a solution with a concentration of 12.8 g per 100 g of water at 20°C. Due to this, the solubility increases with increase in the molecular weight on moving down the group. Let's use MgCO 3 as an example. solubility: sulphates of alkali metals are soluble in water. Correct option: (d) Ba(OH) 2 < Sr(OH) 2 < Ca(OH) 2 < Mg(OH) 2 Explanation: Stability of ionic compounds decreases with decrease in lattice enthalpy. Decomposition temperatures and decomposition enthalpies of the four hydroxides increase with increasing atomic weight of the compounds. Even for hydroxides we have the same observations. Looking at the enthalpy change of formation for group 2 metal oxides itâs clearly less energy is needed to break them as you go down the group. (ii) Thermal stability Alkali and alkaline earth metal nitrates decompose on heating. 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