charge density), there is significant difference in terms of their ability to hydrate. All of the Group 2 sulphates consist of 2+ ions attracting 2- ions, and so the only thing that matters is the distance between the ion centres. Both carbonates and nitrates of Group 2 elements become more thermally stable down the group. Be > Mg > Ca > Sr > Ba. BaSO 4 (s) (thick white precipitate forms); Sr 2+ + SO 4 2-(aq) ? Mg(s) + H2O(g) â MgO(s) + H2(g) b) Calcium is more reactive. The solubility also increases down the group for these compounds i-e., Be(OH)2 is less soluble in water as compared to Ba(OH)2. The greater the distortion caused by the polarising ion the less stable the compound is to heat. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. a) Virtually no reaction occurs between magnesium and cold water. Reactivity increases down the group. Alkaline Earth Metals (Group II Elements), Chemical Properties of Alkaline Earth Metals, Transistor Biasing Circuits and Thermal Stability, Group 2 Elements: Alkaline Earth Metals-General Properties. It also identifies and explains the trend in the solubility and thermal stability of group 2 metal compounds. Ionisation energy decreases due to extra shielding from inner shells and increase in distance from the nucleus. The solubility of the Group 2 sulphates decreases down the group. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. 3.2k VIEWS. Thermal stability: * Carbonates are decomposed to carbon dioxide and oxide upon heating. Even for hydroxides we have the same observations. This is clearly seen if we observe the reactions of magnesium and calcium in water. The solubility of carbonates increases down the group in alkali metals (except ) . c i e n o t e s . Ca(s) + H2O(l) â Ca(OH)2(aq) + H2(g) The thermal decomposition of eleven (II) sulphates has been studied by a combination of thermogravimetric and differential thermal analysis. However, sulphates of alkaline earth metals show varied trends. It reacts with cold water to produce an alkaline solution of calcium hydroxide and hydrogen gas is released. M (OH) 2 + H 2 SO 4 â MSO 4 + 2H 2 O MCO 3 + H 2 SO 4 â MSO 4 + CO 2 + H 2 O . The thermal stability of alkaline earth metals increases down the group for hydroxides i-e., Be(OH)2 is less stable than Ba(OH)2. b) Calcium is more reactive. The resource is set out as teachers' notes followed by the students' page which presents the task to be investigated. Answers of How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? The relative decomposition temperatures are: MnSO 4 755, FeSO 4 537, CoSO 4 708, NiSO 4 675, CuSO 4 598, ZnSO 4 646, CdSO 4 816, PbSO 4 803, MgSO 4 895, CaSO 4 1149, and SrSO 4 1374°C. Alkali Earth Metals Group 1. Whereas bicarbonates give carbonate, water and carbon dioxide. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. Bottom Ba. This means that beryllium carbonate decomposes at a lower temperature to the rest of the group. The solubilities of these salts further increase on descending the group. solubility: sulphates of alkali metals are soluble in water. The thermal stability of the nitrates follows the same trend as that of the carbonates, with thermal stability increasing with proton number. This can be explained by the increase in ease at losing two outer electrons as we descend the group. Sulphates of both group 1 and group 2 metals are stable towards heat. Again the reactivity increases down the group, all forming a white oxide. The larger compounds further down require more heat than the lighter compounds in order to decompose. For Alkaline Earth metals Group 2. Thermal stability is a chemical process whereby the components of the lattice react causing decomposion to more stable products. Solubility of Hydroxides and Flourides INCREASES from top to bottom. As the size of the Group 2 cations increases down the group, the difference between the size of the metal cations and the size of the SO 4 2-ions decreases. This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. The term "thermal decomposition" describes splitting up a compound by heating it. soon. Factors possibly influencing thermal stability of ⦠Thermal decomposition of Group 2 carbonates The ease of thermal decomposition decreases down the group CaCO 3(s) CaO(s) + CO 2(g) Group 2 carbonates decompose on heating to produce group 2 oxides and carbon dioxide gas. You can study other questions, MCQs, videos and tests for NEET on EduRev and even discuss your questions like However, in a reaction with steam it forms magnesium oxide and hydrogen. The reason, once more, is that the polarising power of the M2+ decreases as ionic radius increases. The thermal stability of Group II carbonates increases as we descend the group. are solved by group of students and teacher of NEET, which is also the largest student Top Be. a) Virtually no reaction occurs between magnesium and cold water. Solubility of Carbonates INCREASES(opposite of group 2) from top to bottom. So what causes this trend? Apart from being the largest NEET community, EduRev has the largest solved All of these carbonates are white solids, and the oxides that are produced are also white solids. The relative decomposition temperatures are: MnSO4 755, FeSO4 537, CoSO4 708, NiSO4 675, CuSO4 598, ZnSO4 646, CdSO4 816, PbSO4 803, MgSO4 895, CaSO4 1149, and SrSO4 1374°C. and big group of compounds are stable with big ionic group. over here on EduRev! Thermal decomposition of Group 2 carbonates The ease of thermal decomposition decreases down the group CaCO3(s ) CaO(s) + CO2(g ) Group 2 carbonates decompose on heating to produce group 2 oxides and carbon dioxide gas. The Questions and Reactivity increases down the group. The thermal stability increases down the group for sulphates of alkaline earth metals. The higher the temperature needed to decompose something, the more thermally stable it is. This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. 2.0k SHARES. The correct option is: (a) BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3 Explanation: In all cases, for a particular set of e.g. Charge Density and Polarising Power of Group 2 Metal Cations. EduRev is a knowledge-sharing community that depends on everyone being able to pitch in when they know something. This discussion on How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? Let's use MgCO 3 as an example. | EduRev NEET Question is disucussed on EduRev Study Group ⦠The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. As you go down the Group, the carbonates have to be heated more strongly before they will decompose. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. Li to Na. ⦠Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. This page looks at the effect of heat on the carbonates and nitrates of the Group 2 elements â beryllium, magnesium, calcium, strontium and barium. How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? Hence polarising ability of the M2+ ion decreases down the group. To help you revise your definitions and equations. It however shows reversible decomposition in closed container 000+ LIKES. The carbonates become more stable to heat as you go down the Group. But carbonates of alkaline earth metals are insoluble in water. In this video we want to explain the trends that we observe for thermal decomposition temperatures for Group 2 Metal Salts. The sulphates of alkaline earth metals are all white solids. The greater the charge density the easier it is for the cation to hydrate and hence dissolve in water due to greater attraction with the polar water molecules. Less attractions are formed with water molecules. More the strong bonding more thermal stability. Nitrates of group -1 and group-2 metals are all soluble in water. is done on EduRev Study Group by NEET Students. The thermal decomposition of eleven (II) sulphates has been studied by a combination of thermogravimetric and differential thermal analysis. Thermal stability. As you go down the group, the energy needed to break up the lattice falls as the positive ions get bigger. MgCO 3(s) MgO(s) + CO 2(g) Thermal decomposition is defined as the use of heat to break down a reactant into more than Magnesium sulphate dissolves in water whereas barium sulphate does not. In this microscale chemistry experiment, from the Royal Society of Chemistry, students investigate the solubility of the group 1 and 2 sulphates and carbonates by reacting small amounts of them on a clear plastic sheet over a worksheet. Beryllium carbonate decomposing most easily. The loss of electrons becomes easier due to the decreasing ionisation energy required. In group 1 and 2, the nitrates and carbonates get more stable down the group. Small highly charged positive ions distort the electron cloud of the anion. Solubility of Carbonates and Sulphates DECREASES from top to bottom. All group II elements react in air to form an oxide layer. Due to the large size of the sulphate anion there is little difference between the lattice energies for these compounds. It describes and explains how the thermal stability of the compounds changes as you go down the Group. Properties of Sulphates of Alkali Earth Metals. The sulphate of alkaline earth metals is less soluble. FAQs on Appendix - ⦠The larger the anion the easier the distortion, as seen with the carbonate ion. Jan 07,2021 - How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? (c)Sulphate-thermal stability is good for both alkali and alkaline earth metals. All the enthalpy definitions including Lattice Enthalpy, Enthalpy of Hydration and Enthalpy of solutions. However, in a reaction with steam it forms magnesium oxide and hydrogen. MgSO 4 Soluble. community of NEET. It reacts with cold water to produce an alkaline solution of calcium hydroxide and hydrogen gas is released. 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